INFLUENCE OF ALKALI-FREE AND ALKALINE SHOTCRETE ACCELERATORS WITHIN CEMENT SYSTEMS: HYDRATION, MICROSTRUCTURE, AND STRENGTH DEVELOPMENT

Strength development of mixtures accelerated with alkali-free and alkaline admixtures is clarified. Alkali-free admixtures do not interfere with calcium silicatehydrate gel development. A good dissolution of the admixture (e.g., a calciumsulfoaluminate-rich one) causes the ettringites to be homogeneously distributed within the cementitious mass, thus acting as a crack arrester and enhancing the strength. Conversely, an inhomogeneous distribution of the admixture results in the formation of high voluminous ettringite enrichments that weaken the microstructure and result in the strength decrease of the alkali-free accelerated mixtures. Addition of the alkaline accelerator delays the hydration of the calciumsilicate components to calciumsilicatehydrate gel and its densifying process. As a result, a general high porosity persists up to 6 months, resulting in the lowest strength among the accelerated mixtures.

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  • Accession Number: 00979777
  • Record Type: Publication
  • Files: TRIS
  • Created Date: Oct 5 2004 12:00AM