USE OF A MULTIWAVELENGTH UV-VIS DETECTOR WITH HP-GPC TO GIVE A THREE-DIMENSIONAL VIEW OF BITUMINOUS MATERIALS
High performance gel permeation chromatography (HP-GPC) is being used in the study of asphalt cements. The use of a photodiode array spectrophotometric detector adds to the chemical information that may be obtained from the HP-GPC molecular size distribution by providing chromatograms at multiple wavelengths in the ultraviolet-visible range simultaneously. A three-dimensional image of the asphalt and spectra at various elution times are obtained. The result is improved knowledge of the conjugation/aromaticity of asphalt components of various hydrodynamic volumes. In this study, a group of 19 asphalt cements, from worldwide sources and representing a broad range of properties, was selected for eventual construction of a data base. These materials were sorted into three classes based on their chromatographic shapes. These classes appear to extend to temperature susceptibility (PVN) and aging index as well. Also investigated were a limited number of less common materials to determine the potential utility of the technique. These materials included SARA fractions, viscosity-reduced, air-blown and solvent-deasphalted residua.
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Availability:
- Find a library where document is available. Order URL: http://worldcat.org/isbn/0309048230
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Supplemental Notes:
- This paper appears in Transportation Research Record No. 1228, Asphalt Mixtures and Asphalt Chemistry. Distribution, posting, or copying of this PDF is strictly prohibited without written permission of the Transportation Research Board of the National Academy of Sciences. Unless otherwise indicated, all materials in this PDF are copyrighted by the National Academy of Sciences. Copyright © National Academy of Sciences. All rights reserved
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Authors:
- Pribanic, Joan A S
- Emmelin, Mark
- King, Gayle N
- Publication Date: 1989
Media Info
- Features: Figures; References;
- Pagination: p. 168-176
- Monograph Title: Asphalt mixtures and asphalt chemistry
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Serial:
- Transportation Research Record
- Issue Number: 1228
- Publisher: Transportation Research Board
- ISSN: 0361-1981
Subject/Index Terms
- TRT Terms: Asphalt cement; Bituminous materials; Databases; Detectors; Electromagnetic waves by wavelength; Gel permeation chromatography; Mathematical models; Performance; Spectrophotometers
- Uncontrolled Terms: High performance
- Old TRIS Terms: Multiwavelength uv-vis detectors
- Subject Areas: Design; Highways; Materials; Pavements; I22: Design of Pavements, Railways and Guideways; I23: Properties of Road Surfaces; I31: Bituminous Binders and Materials;
Filing Info
- Accession Number: 00495100
- Record Type: Publication
- ISBN: 0309048230
- Files: TRIS, TRB, ATRI
- Created Date: Jun 30 1990 12:00AM