INFRARED LASER ENHANCED REACTIONS: O3 + SO
Vibrationally excited ozone, O3 produced by CO2 laser radiation was found to react with SO significantly faster than thermal ozone via the chemiluminescent reaction process O3 + SO to SO2 (singlet B(1)) + O2 (triplet Sigma (g)). The vibrational rate enhancement of this reaction was 2.5 plus or minus 0.6 at 300 K. This represents the use of 27% of the available vibrational energy to promote the reaction, based on a model assuming involvement of a single vibrational mode. The laser enhanced chemiluminescence measured from 260 to 450 nm was found to exhibit a 630 plus or minus 200/cm blue shift. This is interpreted as a partitioning of the available vibrational energy of O3 in the vibrational manifold of the SO2 (singlet B(1)) product.
- Sponsored inpart by Department of Transportation, Washington, D.C., Climatic Impact Assessment Program. Originally published in Journal of Chemical Physics, V61, N7, pp 2426-2499, 1 October 1974.
National Bureau of Standards14th Between E Street and Constitution Avenue, NW
Washington, DC USA 20234
Department of TransportationClimatic Impact Assessment Program, 1200 New Jersey Avenue, SE
Washington, DC USA 20590
- Kaldor, A
- BRAUN, W
- Kurylo, M J
- Publication Date: 1974-10-1
- Pagination: 4 p.
- TRT Terms: Chemiluminescence; Excitation; Kinetics; Molecular structure; Motor reactions; Ozone; Vibration
- Old TRIS Terms: Molecular vibration; Reaction kinetics; Sulfur monoxide
- Subject Areas: Safety and Human Factors;
- Accession Number: 00090021
- Record Type: Publication
- Source Agency: National Technical Information Service
- Report/Paper Numbers: Final Rpt.
- Files: NTIS, USDOT
- Created Date: Nov 18 1975 12:00AM