Effects of n-Heptane as a Promoter for Auto-ignition Reaction of Toluene and Analysis of Reaction Products

Toluene の自着火過程におけるn-Heptane 添加の反応促進効果および 自着火過程で生成される化合物の検討

A comprehensive two-dimensional gas chromatography with time-of-flight mass spectrometer (GCxGC-TOFMS) was used for analysis of gas composition in a constant volume combustion chamber before ignition. Influences of mixture temperature on reaction products from toluene/O₂/Ar were investigated by varying mixture temperature from 450 to 510K. From the detected signal of benzaldehyde, it was indicated that oxidation reaction of toluene was accelerated by temperature rising. From comparison between toluene/O₂/Ar and 20mol%toluene+80mol%n-heptane/O₂/Ar, it was indicated that the reaction of n-heptane accelerated the consumption of toluene. In addition, it was suggested that heptanedione was important product of low temperature reaction of alkanes.定容燃焼容器内に3min保持した混合気について，飛行時間型質量分析計を備えた包括的2DGCを用いて生成物を分析した結果，n-heptaneの酸化反応がtolueneの酸化反応を加速することがわかった．また，低温酸化反応の生成物としてdiketoneの重要性が示唆された．

• Record URL:
  https://doi.org/10.11351/jsaeronbun.49.30
• Record URL:
  http://scholar.google.com/scholar_lookup?title=Effects%20of%20n-Heptane%20as%20a%20Promoter%20for%20Auto-ignition%20Reaction%20of%20Toluene%20and%20Analysis%20of%20Reaction%20Products&author=M.%20Nakano&author=R.%20Tomata&author=M.%20Inage&author=R.%20Shinya&author=K.%20Kono&author=J.%20Hou&author=Y.%20Nagano&author=T.%20Kitagawa&publication_year=2018
• Availability:
  • Find a library where document is available. Order URL: http://worldcat.org/issn/02878321
• Authors:
  • Nakano, Michio
  • Tomata, Ryo
  • Inage, Motohiro
  • Shinya, Ryo
  • Kono, Kenta
  • Hou, Junfeng
  • Nagano, Yukihide
  • Kitagawa, Toshiaki
• Publication Date: 2018-1

Language

• English
• Japanese

Media Info

• Media Type: Digital/other
• Features: Figures; References; Tables;
• Pagination: pp 30-35
• Serial:
  • Transactions of Society of Automotive Engineers of Japan
  • Volume: 49
  • Issue Number: 1
  • Publisher: Society of Automotive Engineers of Japan
  • ISSN: 0287-8321
  • EISSN: 1883-0811
  • Serial URL: https://www.jstage.jst.go.jp/browse/jsaeronbun
• Publication flags:

  Open Access (libre)

Subject/Index Terms

• TRT Terms: Alkanes; Combustion; Combustion chambers; Combustion efficiency; Fuel additives; Fuel mixtures; Gas chromatography; Mass spectrometry; Oxidation; Oxygen; Spark ignition engines; Temperature; Toluene
• Subject Areas: Energy; Highways; Vehicles and Equipment;

Filing Info

• Accession Number: 01660605
• Record Type: Publication
• Source Agency: Japan Science and Technology Agency (JST)
• Files: TRIS, JSTAGE
• Created Date: Feb 20 2018 9:32AM