APPLICATION OF BEAM SAMPLING MASS SPECTROMETRY TO THE KINETICS OF OZONE REACTIONS

A beam sampling mass spectrometer designed for the study of chemical reactions in the gas phase is described. It is a three stage, differentially pumped instrument using a molecular beam chopper and phase sensitive detection. The reactions of ozone with NO2 and some olefins were studied using a temperature controlled stopped-flow reactor in conjunction with the beam sampling mass spectrometer.

• Supplemental Notes:
  • Sponsored in part by Department of Transportation, Washington, D.C. Climatic Impact Assessment Program. NTIS #COM-75-50302/9ST. Pub. in International Jnl. of Mass Spectrometry and Ion Physics, v16 n1/2 p125-136 1975.
• Corporate Authors:

  National Bureau of Standards

  14th Between E Street and Constitution Avenue, NW
  Washington, DC  United States  20234

  Department of Transportation

  Climatic Impact Assessment Program, 1200 New Jersey Avenue, SE
  Washington, DC  United States  20590
• Authors:
  • Herron, J T
  • Huie, R E
• Publication Date: 1975

Media Info

• Pagination: 12 p.

Subject/Index Terms

• TRT Terms: Chemical reactions; Hydrocarbons; Kinetics; Mass spectrometers; Molecular structure; Motor reactions; Nitrogen dioxide; Ozone; Particle beams
• Old TRIS Terms: Alkenes; Molecular beams; Reaction kinetics
• Subject Areas: Safety and Human Factors;

Filing Info

• Accession Number: 00091344
• Record Type: Publication
• Source Agency: National Technical Information Service
• Report/Paper Numbers: Final Rpt.
• Files: NTIS, USDOT
• Created Date: Jul 15 1975 12:00AM