Morphological, thermochemical, and rheomechanical evaluation of self-healing performance of asphalt binder modified with hybrid-structured phase change material capsules

Currently, sustainable pavement research focuses on modified asphalt binders with self-healing features for achieving durability and safety goals. This study assesses the self-healing behavior of asphalt binders incorporating innovative lab-manufactured hybrid-structured phase change material capsules (HPCMC). The HPCMC, using by-product paraffin oil as a core encapsulated by waste nano-silica fume as a shell, varied in core-to-shell ratios (0.5:1, 1:1, 2:1) and dosages (1 %, 3 %, 5 %, 7 %) by asphalt weight. Morphological, thermal, and chemical characterizations were conducted using scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermal gravimetric analysis (TGA), and Fourier transform infrared spectroscopy (FTIR). Healing efficiency of unaged and short-term aged HPCMC-modified binders was evaluated using SEM and energy dispersive X-ray (EDX) for morphological and chemical analysis. Rheomechanics were examined through rotational viscosity (RV), performance grading (PG), multiple stress creep recovery (MSCR), strain sweep (SS), frequency sweep (FS), linear amplitude sweep (LAS), and linear amplitude sweep-based healing (LASH). Study findings exhibit superior healing in HPCMC-modified binders compared to unmodified ones, particularly at a 3 % dosage and 1:1 core-to-shell ratio in unaged conditions. This study also evaluates healing assessment criteria and validates the self-healing mechanism, indicating significant potential for the proposed approach to revolutionize pavement construction and maintenance.

• Record URL:
  • https://doi.org/10.1016/j.conbuildmat.2024.137246
• Record URL:
  • http://www.sciencedirect.com/science/article/pii/S0950061824023882
• Availability:
  • Find a library where document is available. Order URL: http://worldcat.org/issn/09500618
• Supplemental Notes:
  • © 2024 Elsevier Ltd. All rights are reserved, including those for text and data mining, AI training, and similar technologies. Abstract reprinted with permission of Elsevier.
• Authors:
  • Tarbay, Eman W
  • 0009-0003-7773-3165
  • Ragab, A A
  • 0000-0002-7843-8040
  • Gabr, Alaa R
  • 0000-0002-2399-2271
  • El-Badawy, Sherif M
  • 0000-0001-8348-1580
  • Awed, Ahmed M
  • 0000-0001-7951-1636
• Publication Date: 2024-8-23

Language

• English

Media Info

• Media Type: Web
• Features: References;
• Pagination: 137246
• Serial:
  • Construction and Building Materials
  • Volume: 440
  • Issue Number: 0
  • Publisher: Elsevier
  • ISSN: 0950-0618
  • Serial URL: http://www.sciencedirect.com/science/journal/09500618?sdc=1

Subject/Index Terms

• TRT Terms: Asphalt; Morphology; Phase transitions; Rheological properties; Self-healing materials; Thermal properties
• Subject Areas: Highways; Materials; Pavements;

Filing Info

• Accession Number: 01926796
• Record Type: Publication
• Files: TRIS
• Created Date: Aug 9 2024 3:31PM