Effect of Cyclo-Pentane Impurities on the Autoignition Reactivity and Properties of a Gasoline Surrogate Fuel

Surrogate fuels that reproduce the characteristics of full-boiling range fuels are key tools to enable numerical simulations of fuel-related processes and ensure reproducibility of experiments by eliminating batch-to-batch variability. Within the PACE initiative, a surrogate fuel for regular-grade E10 (10%vol ethanol) gasoline representative of a U.S. market gasoline, termed PACE-20, was developed and adopted as baseline fuel for the consortium. Although extensive testing demonstrated that PACE-20 replicates the properties and combustion behavior of the full-boiling range gasoline, several concerns arose regarding the purity level required for the species that compose PACE-20. This is particularly important for cyclo-pentane, since commercial-grade cyclo-pentane typically shows 60%–85% purity. In the present work, the effects of the purity level of cyclo-pentane on the properties and combustion characteristics of PACE-20 were studied. Chemical kinetic simulations were performed to predict the effects of cyclo-pentane impurities on the properties, octane rating, and autoignition reactivity under homogeneous charge compression-ignition conditions of PACE-20. From the numerical results, cyclo-pentane with 85% purity or higher is required to reasonably match both the research octane number and motor octane number of the target gasoline. Finally, homogeneous charge compression-ignition engine simulations show that impurities have only a modest effect on reactivity at naturally aspirated conditions, but cyclo-pentane purity is critical to properly replicate the pressure dependency of the reactivity.

• Record URL:
  • https://doi.org/10.4271/2024-01-5021
• Availability:
  • Find a library where document is available. Order URL: http://worldcat.org/issn/01487191
• Supplemental Notes:
  • Abstract reprinted with permission of SAE International.
• Authors:
  • Lopez-Pintor, Dario
  • Abboud, Rami
  • MacDonald, James
  • Lee, Sanguk
• Conference:
  • Automotive Technical Papers
  • Location: Warrendale Pennsylvania
  • Date: 2024-1-1
• Publication Date: 2024-2-6

Language

• English

Media Info

• Media Type: Web
• Features: References;
• Serial:
  • SAE Technical Paper
  • Publisher: Society of Automotive Engineers (SAE)
  • ISSN: 0148-7191
  • EISSN: 2688-3627
  • Serial URL: http://papers.sae.org/

Subject/Index Terms

• TRT Terms: Combustion; Ethanol; Gasohol; Gasoline; Simulation
• Subject Areas: Highways; Vehicles and Equipment;

Filing Info

• Accession Number: 01908745
• Record Type: Publication
• Source Agency: SAE International
• Report/Paper Numbers: 2024-01-5021
• Files: TRIS, SAE
• Created Date: Feb 20 2024 9:59AM