Corrosion of galvanized steel in alkaline solution associated with sulfate and chloride ions
Corrosion mitigation strategies for structural steel bridge elements including post tensioned steel components include the use of galvanized steel. The zinc alloy layers and subsequent precipitation of a dense surface oxide in alkaline environments provide beneficial barrier protection to mitigate corrosion. However, severe corrosion of galvanized steel components in contact with sulfate-rich deficient cementitious grout was documented to occur in less than 8 years of bridge service. Electrochemical testing and material characterization showed that the presence of sulfates in alkaline solutions allow for prolonged zinc activity and hindered passivation by the incomplete surface coverage and the precipitation of large sized calcium hydroxy zincate. OCP, LPR, and electrochemical noise (EN) testing showed greater corrosion activity of galvanized steel in chloride and sulfate solutions. EN identified local corrosion activity of the zinc associated to the porous nature of the surface oxide layer.
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Availability:
- Find a library where document is available. Order URL: http://worldcat.org/issn/09500618
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Supplemental Notes:
- © 2023 Elsevier Ltd. All rights reserved. Abstract reprinted with permission of Elsevier.
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Authors:
- Permeh, Samanbar
- Lau, Kingsley
- Publication Date: 2023-8-15
Language
- English
Media Info
- Media Type: Web
- Features: References;
- Pagination: 131889
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Serial:
- Construction and Building Materials
- Volume: 392
- Issue Number: 0
- Publisher: Elsevier
- ISSN: 0950-0618
- Serial URL: http://www.sciencedirect.com/science/journal/09500618?sdc=1
Subject/Index Terms
- TRT Terms: Alkali; Chlorides; Corrosion; Galvanized metals; Ions; Steel bridges; Sulfates
- Subject Areas: Bridges and other structures; Highways; Maintenance and Preservation;
Filing Info
- Accession Number: 01886218
- Record Type: Publication
- Files: TRIS
- Created Date: Jun 28 2023 4:29PM