The Effects of Oil-Derived Poisons on Three-Way Catalyst Performance

Two major deactivation mechanisms of automotive catalysts during road usage are: A dynamometer-based aging cycle, incorporating a high-temperature low-poison mode to account for thermal aging followed by a low-temperature high-poison mode to account for poison accumulation, has been developed to allow the examination of catalyst formulations after exposure to both a harsh thermal and chemical aging environment. This type of aging cycle results in dynamometer-aged catalysts that are physically much more similar to road-aged catalysts than thermally-based dynamometer cycles. Using this aging-cycle, Pd-only, Pd-Rh and Pt-Rh light-off catalysts were examined. The Pd-Rh catalyst gave the best overall performance, with equivalent HC light-off performance to the Pd-only catalyst and equivalent NOx performance to the Pt-Rh catalyst.

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  • English

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Filing Info

  • Accession Number: 01800188
  • Record Type: Publication
  • Source Agency: SAE International
  • Report/Paper Numbers: 2002-01-1093
  • Files: TRIS, SAE
  • Created Date: Dec 9 2021 10:21AM